Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals.
This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds.
Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.
This title is written for organic chemists and offers an easy entry into the field of organotransition metal chemistry without requiring a background in inorganic chemistry. A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics.
Well illustrated with figures and formulae. This textbook introduces students and experienced chemists to a rapidly growing interdisciplinary subject. It incorporates a thorough revision of the earlier edition, and includes all new developments.
Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis deals with the chemistry of organo-transition metal complexes and their uses as homogeneous catalysts and as intermediates in organic synthesis.
The compounds are classified mainly from the number of carbon atoms that are actually bonded to the metal and to each other. This volume is comprised of eight chapters and begins with a discussion on alkyls, aryls, acetylides, fluorocarbon complexes, and carbides, along with olefin, allene, and acetylene complexes. Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes.
This book will be a valuable source of information for inorganic chemists. Organometallics playa key role in organic synthesis. From the wealth of carbon carbon bond forming reactions in organotransition metal chemistry many new methods have evolved. This was aided considerably by a deepening of our understanding of the relevant reaction mechanisms.
Organometallic chemistry is the bridge par excellence between the traditional fields of inorganic and organiC chemistry. From its very beginning this program grew up after 6 years to now more than 60 projects and its encompasses besides its main topic "Organic Synthesis" mechanistic and structural aspects of organometallic chemistry as well.
In a series of symposia sponsored by the "Volkswagen-Stiftung", the former of which were held in Hamburg February , Wiirzburg October and Marburg July , a forum for intensive discussions and SCientific exchange was established. There, scientists participating in the program met with other experts form academia and from industry. The forth symposium was held in Aachen from July 15 to 18, This unusual collection of 49 essays gives an overview of the trends and accomplishments of synthetic organic chemistry in recent years.
Unique in its approach, it deals with almost every aspect of modern synthesis. This book presents a practical introduction into the organic syntheses using organometallic reagents and catalysts. Addressing the most important issues, it restricts itself to the derivatives of less than a dozen metals, focusing on those which are most versatile and frequently used. Print book: EnglishView all editions and formats Summary: Outlines the main classes of transition metal organometallic complexes and introduces the reader to the chemistry of compounds with metal-carbon s-bonds: metal carbonyls, metal alkyls, and metal alkylidenes and alkylidenes.
Organometallics Grignards, alkyl lithiums, organocuprates. Using the retrosynthesis technique to solve synthesis problems involving organocuprates. Some courses may not. Historical development and current trends in organometallic chemistry Demarcation and classification of organometallic compounds Energy, polarity and reactivity of the M-C bond Main-group organometallics Methods of preparation in perspective Alkali organometallics Organometallics of groups 2 and 12 Organometallics of the boron group group Organometallic definition is - of, relating to, or being an organic compound that usually contains a metal or metalloid bonded directly to carbon.
With the demand to synthesize highly complex natural products and obtain new chemical structures for probing uncharted chemical space, organometallic reagents have become a critical partner in the formation of known bond formations e. Organometallic chemistry continues to be a highly active area of chemistry all across Asia.
This special issue presents a topical and broad spectrum of original research papers showcasing some of the most significant and contemporary organometallic chemistry research happening across the continent. As a graduate student in organometallic chemistry, this is an excellent book. I highly recommend this book. This Third Manual of Organometallics in Synthesis features completely new content and topics, ebook an eye towards providing researchers with the most useful and practical reference on the synthesis of organometallics.
Last edited by Mezragore. Organometallics 1 complexes with transition metal-carbon [sigma]-bonds by Manfred Bochmann Want to read 4 Currently reading Published by Oxford University Press in Oxford. Share this book. The Irish rebellion. Services for those with acquired brain damage.
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A Practical Guide. Chemometrics: A Practical Guide. Heterocyclic Compounds: Synthesis, Properties and Applications. Recommend Documents. Synthesis of Organometallic Compounds Garnovskii and Boris Your name. Close Send.
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